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Updated on 20th October, 2023 , 3 min read
Cathode and Anode are both defined by the flow of current. Therefore, a cathode is an electrode from which the current exits a polarized electrical device. Likewise, an anode is an electrode from which a current enters into a polarized electrical device.
Anode and cathode are the two types of electrodes
An anode is a place from where electricity passes through in a cell. It is a point where oxidation takes place. Anodes react and give off the electrons by which they can go into the driving circuit.
In the most basic form, an anode in electrochemistry is the point where an oxidation reaction occurs. Generally, at an anode, negative ions or anions due to its electrical potential tend to react and give off electrons. These electrons then move up and into the driving circuit.
A simple example is electrolysis of water. A positively charged platinum electrode where H2 gas is oxidized to H+ ions is the anode.
The anode is the positive terminal that receives current from an external generator in a recharging battery. The current through a battery flows in an opposite direction of the current during discharge in the recharging battery.
A cathode is a place from where electricity leaves through a cell. It is a point where reduction takes place. This is common in an electrochemical cell.
Generally, the cathode is the electrode where reduction reaction takes place. This means the cathode gains electrons from the external circuit and gets reduced.
There are two types of cathodes:
Cold cathodes: Cathodes that are not electrically heated by a filament. Which emits more electrons than can be supplied by thermionic emission are called cold cathodes.
Hot cathodes: Cathodes are heated by electric current passing through the filament.
Electrolytic Cell
In an electrolytic cell, the cathode is where the negative polarity is applied. Some results of reduction at the cathode are pure metal or hydrogen gas from metal ions.
Galvanic Cell
In a galvanic cell, the cathode is the positive pole. This positive pole is connected to allow the circuit to be completed. The anode of the galvanic cell gives off electrons and return from the circuit into the cell through the cathode.
Electroplating Metal Cathode (Electrolysis)
When metal ions are reduced, they form a pure metal surface on the cathode. Items to be plated with pure metal are attached and become part of the cathode in the solution.
Here are some key differences between cathode and anode.
Anode | Cathode |
| The anode is the electrode where electricity moves into. | The cathode is the electrode where electricity is given out or flows out. |
| The anode is usually the positive side. | A cathode is a negative side. |
| It acts as an electron donor. | It acts as an electron acceptor. |
| In an electrolytic cell, oxidation reaction takes place at the anode. | In an electrolytic cell, a reduction reaction takes place at the cathode. |
| In galvanic cells, an anode can become a cathode. | In galvanic cells, a cathode can become a |
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By - Nikita Parmar 2023-08-25 09:48:44 , 11 min readOxidation response at the anode. The oxidized species lose electrons by leaving electrode with an accumulation of electrons. Therefore, the anode has a negative charge. In contrast, a cathode is a reduction response where the decreased species obtain electrons. Therefore, the electrode, i.e., the cathode, lacks electrons and has a positive charge.
Cathodes are generally being labeled in LEDs. It should be linked to the driving voltage source’s floor. It should be on the adverse side. Also, the anode should be at the positive side.
During the corrosion phase, iron-based metal serves as the anode in galvanic cells. At the cathode electrode, it can oxidize to Fe2+. Oxygen can decrease to water.
In general, a positive electrode can be defined as a cathode whereas a negative electrode can be defined as an anode.
Iron metal functions as the anode in a galvanic cell during the corrosion phase and is oxidized to Fe2+; at the cathode, oxygen is decreased to water.
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